Transition Metals in the Synthesis of Complex Organic Molecules, 3/e (Hardcover)

Louis Hegedus, Bjorn Soderberg

  • 出版商: University Science
  • 出版日期: 2009-07-29
  • 售價: $1,860
  • 貴賓價: 9.8$1,823
  • 語言: 英文
  • 頁數: 480
  • 裝訂: Hardcover
  • ISBN: 1891389599
  • ISBN-13: 9781891389597
  • 下單後立即進貨 (約5~7天)

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<內容簡介>

The third edition of Transition Metals in the Synthesis of Complex Organic Molecules is a comprehensive revision and significant expansion of the second edition. The clear and systematic approach to the formation, manipulation, and reactivity of organometallic complexes has been maintained. The book is divided into 10 chapters starting with general formalisms, electron counting, and basic principles of organometallic reaction mechanisms. The organic chemistry of transition metals is then presented by class of metal complex, with many examples of applications in the synthesis of complex natural products and pharmaceuticals. The book is ideal for advanced undergraduate and graduate students as well as all practicing synthetic organic chemists. It is written for organic chemists and offers an easy entry into the field of organotransition metal chemistry without requiring a background in inorganic chemistry.
<章節目錄>

1. Formalisms, Electron Counting, Bonding (How Things Work)

2. Organometallic Reaction Mechanisms

3. Synthetic Applications of Transition Metal Hydrides

4. Synthetic Applications of Complexes Containing Metal-Carbon Sigma-Bonds

5. Synthetic Applications of Transition Metal Carbonyl Complexes

6. Synthetic Applications of Transition Metal Carbene Complexes

7. Synthetic Applications of Transition Metal Alkene, Diene, and Dienyl Complexes

8. Synthetic Applications of Transition Metal Alkyne Complexes

9. Synthetic Applications of eta3-Allyl Transition Metal Complexes

10. Synthetic Applications of Transition Metal Arene Complexes

11. Reactions of eta6-Arenemetal Complexes

Index

商品描述(中文翻譯)

內容簡介:

《過渡金屬在複雜有機分子合成中的應用》第三版是第二版的全面修訂和重要擴充。本書保持了對有機金屬配合物形成、操作和反應性的清晰和系統化方法。本書分為10章,從一般形式、電子計數和有機金屬反應機理的基本原理開始。然後按金屬配合物的類別介紹過渡金屬的有機化學,並提供了許多在複雜天然產物和藥物合成中的應用示例。本書適合高年級本科生、研究生以及所有實踐合成有機化學家使用。它針對有機化學家撰寫,無需有無機化學背景即可輕鬆進入有機過渡金屬化學領域。

章節目錄:

1. 形式、電子計數、鍵結(工作原理)
2. 有機金屬反應機理
3. 過渡金屬氫化物的合成應用
4. 含金屬-碳σ鍵的配合物的合成應用
5. 過渡金屬羰基配合物的合成應用
6. 過渡金屬卡賓配合物的合成應用
7. 過渡金屬烯烴、二烯和二烯基配合物的合成應用
8. 過渡金屬炔烴配合物的合成應用
9. 過渡金屬η3-烯丙基配合物的合成應用
10. 過渡金屬芳烴配合物的合成應用
11. η6-芳烴金屬配合物的反應
索引